ABSTRACT
The pandemic of COVID-19 disease has brought many challenges in the field of personal protective equipment. The amount of disposable surgical masks (DSMs) consumed increased dramatically, and much of it was improperly disposed of, i.e., it entered the environment. For this reason, it is crucial to accurately analyze the waste and identify all the hazards it poses. Therefore, in the present work, a DSM was disassembled, and gravimetric analysis of representative DSM waste was performed, along with detailed infrared spectroscopy of the individual parts and in-depth analysis of the waste. Due to the potential water contamination by micro/nanoplastics and also by other harmful components of DSMs generated during the leaching and photodegradation process, the xenon test and toxicity characteristic leaching procedure were used to analyze and evaluate the leaching of micro/nanoplastics. Micro/nanoplastic particles were leached from all five components of the mask in an aqueous medium. Exposed to natural conditions, a DSM loses up to 30% of its mass in just 1 month, while micro/nanoplastic particles are formed by the process of photodegradation. Improperly treated DSMs pose a potential hazardous risk to the environment due to the release of micro/nanoparticles and chloride ion content.
ABSTRACT
Enzyme-assisted hydrolysis is frequendy used as a cost-effective and efficient method to obtain functional ingredients from bioresources. This study involved die enzyme-assisted hydrolyzation and purification of fucoidan from Ecklonia maxima stipe and die investigation of its anti-inflammatory activity in lipopolysaccharide (LPS)-induced RAW 264.7 cells. Fucoidans of Viscozyme-assisted hydrolysate from E. maxima (EMSFs) harvested in Jeju, Korea. Structural and chemical characterizations were performed using fourier transform infrared spectroscopy, scanning electron microscope, and monosaccharide analysis. Among fucoidans, EMSF6 was rich in fucose and sulfate and had a similar structural character to commercial fucoidan. EMSF6 showed a strong inhibitory effect on nitric oxide generation in LPS-induced RAW 264.7 cells and significantly decreased die production of LPS-induced pro-inflammatory cytokines, including interleukin-6, interleukin-1 p, and tumor necrosis factor a. The anti-inflammatory potential of EMSF6 was mediated through the down-regulation of inducible nitric oxide synthase and cyclooxygenase-2 expression. Thus, fucoidans from&temppound;. maxima stipe are promising candidates for functional food products.
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This paper demonstrates the need and potential for using waste heat recovery (WHR) systems from infrared gas radiant heaters, which are typical heat sources in large halls, due to the increasing energy-saving requirements for buildings in the EU and the powerful and wide-spread development of the e-commerce market. The types of gas radiant heaters are discussed and the classification of WHR systems from these devices is performed. The article also presents for the first time our innovative solution, not yet available on the market, for the recovery of heat from the exhaust gases of ceramic infrared heaters. The energy analysis for an industrial hall shows that this solution allows for environmental benefits at different levels, depending on the gas infrared heater efficiency, by reducing the amount of fuel and emissions for domestic hot water (DHW) preparation (36.8%, 15.4% and 5.4%, respectively, in the case of low-, standard- and high-efficiency infrared heaters). These reductions, considering both DHW preparation and hall heating, are 16.1%, 7.6% and 3.0%, respectively. The key conclusion is that the innovative solution can spectacularly improve the environmental effect and achieve the highest level of fuel savings in existing buildings that are heated with radiant heaters with the lowest radiant efficiency.
ABSTRACT
Featured ApplicationThis research aims at understanding the sources of plastic litter in a freshwater body, assessing the possible production of secondary microplastics (MPs).Plastic waste dispersion is a well-recognized environmental threat, despite continuous efforts towards improving waste disposal management over the last few decades. Plastic litter is known to strongly impact upon water bodies and shorelines, affecting the health of ecosystems and impacting upon the aesthetic value of sites. Moreover, plastic waste that is abandoned on beaches contributes towards different degradation processes that potentially lead to the formation of secondary microplastics (MPs), with likely cascade effects upon the whole ecosystem. In this view, this study aims to characterize the plastic beach litter found on the shores of the western basin of Como Lake (Italy) to better understand the origin of MPs in littoral sediments, including the recognition of object typologies and the chemical characterization of polymers using Fourier-transformed infrared analysis (FTIR). The results highlighted that the most abundant polymers on beaches are polypropylene (PP) and polyethylene (PE), representing 73% of the collected polymers. This confirms that floating, low-density polymers are more likely to accumulate on beaches. Moreover, almost 66% of litter is represented by commonly used manufactured items (disposable objects, packaging, and everyday items). This evidence, combined with the analysis of the main environmental features of the sampling sites (the main winds, distance to urban areas, and the presence of tributaries) indicate that abundance of beached litter is mainly linked to beach accessibility and the local winds. These results highlight that multiple factors affect the environmental fate of plastic litter and give insights into the assessment of secondary microplastics in beach sediments.
ABSTRACT
Rich in quercetin, shallot (Allium cepa L.) use is beneficial in controlling the COVID-19 pandemic since effective vaccines and pharmacotherapy are still in development. The study aimed to characterize functional groups of shallot tubers planted in the inorganic soil of the seasonal freshwater-wetland (IS-SFW)/Ts-of-RAMSAR-classification ecosystem. The shallot tubers that grew in IS-SFW for 60 days were manually harvested, sun-dried for seven days, and stored for two months before been pressed to produce sample juices. The peaks of wavenumber resulted from FTIR analysis were compared to the infrared database to determine possibly functional groups. The findings showed spectra changed in the fingerprint but not in the mid-IR other regions, indicated the IS-SFW did not affect functional groups beneficial in the COVID-19 treatment. The study concluded that shallot planted in IS-SFW is still beneficial in the COVID-19 treatment.
ABSTRACT
In order to meet the environmental needs caused by large plastic waste accumulation, in the road construction sector, an effort is being made to integrate plastic waste with the function of polymer into asphalt mixtures;with the purpose of improving the mechanical performance of the pavement layers. This study focuses on the effect of a recycled mixture of plastic waste on the chemical, thermal, and rheological properties of designed asphalt blends and on the identification of the most suitable composition blend to be proposed for making asphalt mixture through a dry modification method. Thermo-gravimetric analysis, differential scanning calorimetry, and Fourier transform infrared spectroscopy analysis were carried out to investigate the effect of various concentrations and dimensions of plastic waste (PW) on the neat binder (NB). The frequency sweep test and the multiple stress creep and recovery test were performed to analyze the viscoelastic behavior of the asphalt blends made up of PW in comparison with NB and a commercial modified bitumen (MB). It has been observed that the presence of various types of plastic materials having different melting temperatures does not allow a total melting of PW powder at the mixing temperatures. However, the addition of PW in the asphalt blend significantly improved the aging resistance without affecting the oxidation process of the plastic compound present in the asphalt blend. Furthermore, when the asphalt blend mixed with 20% PW by the weight of bitumen is adopted into the asphalt mixture as polymer, it improves the elasticity and strengthens the mixture better than the mixture containing MB.